Colbert has featured the former White Stripe on "The Colbert Report" all week during his "rock odyssey" series, "Dr. Pepper Presents StePhest ColbChella `011 - Rock You Like a Thirst-Icane."
On Wednesday's program, White agreed to produce a song for Colbert through his record label, the Nashville-based Third Man Records.
White said he would pair Colbert with a Third Man act, the goth girl rock band Black Belles. They're to perform on the program Thursday night, and Colbert has promised to join them.
This is White's second collaboration with a late-night talk show host. Last year he released a live rockabilly album with Conan O'Brien.
