Police say 26-year-old Ethien Rosario and the victim met around 3:15 a.m. Saturday at the Wawa at 500 Route 38.
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They left in the victim's car to an undetermined location where the assault took place, police said.
After the suspect left, the victim returned home and notified police.
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Rosario, of Sicklerville, was arrested on Friday.
He is being charged with sexual assault, kidnapping and carjacking.