Firefighters were called to the scene at 9:15 a.m.
Flames and thick smoke poured from the roof of the building on the 700 block of Stanton-Christiana Road.
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The large building, which is located in an industrial area near railroad tracks, quickly went to two alarms.
The view from Chopper 6 showed smoke billowing into the sky.
Chopper 6 video of business fire in Stanton, Delaware
One firefighter was believed to have been injured from falling on the ice that developed from the water used to battle the blaze.
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There has been no word on any other injuries.
The cause of the fire is under investigation.
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