Police say it happened around 5:30 a.m. on the 2400 block of North 29th Street in the city's Strawberry Mansion neighborhood.
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At the scene, officers found a 43-year-old woman who had been shot in the face inside the store.
She was pronounced dead at the scene. Officials have not released her identity at this time.
No arrests have been made, but police are searching for a male suspect.
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He is described as being tall, between 5'8" and 6'1", with a thin build.
He was last seen in a gray hoodie with white letters on it, black Nike shorts, and white and black sneakers.
Police also say he may drive a silver and gold Nissan Pathfinder with a ladder on top.