It happened around 5 a.m. near the Vine Street Expressway in Northern Liberties.
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The crash involved a van that burst into flames. Police said the driver crashed into the exit divider.
Fatal crash shuts down portion of I-95 in Philadelphia
A portion of southbound I-95 had been shut down as police investigate. It has since reopened.
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The name of the driver who was killed has not been released.