The crash occurred shortly before 5 a.m. Sunday near the Broad Street Exit.
Police say a man in his 30s was ejected from one of the vehicles.
Medics performed CPR on the victim as he was being taken to the hospital.
Two others were also taken to the hospital. One is listed in critical condition, the other is stable.
Police were diverting all I-95 southbound traffic off at the Broad Street Exit. The crash scene was cleared around 9 a.m.
Crash on I-95 in South Philadelphia
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