It happened around 3:30 p.m. on the 1000 block of West Wingohocking Street in the city's Logan section.
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Police say a 40-year-old man and a 26-year-old woman were shot multiple times.
The woman suffered multiple gunshot wounds to her face, police said.
She was pronounced dead at the hospital.
The male victim is listed as critical.
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No arrests have been made.
Anyone with information is asked to call police at 215-686-TIPS.