It happened around midnight Thursday on the 1800 block of South 58th Street.
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Police say someone walked up to the victim and shot him at point-blank range.
The bullets were fired through the driver's side window.
The victim managed to get out of the vehicle. Officers found him lying on the street.
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He was rushed to the Penn Presbyterian Medical Center, but later died from his injuries.
Police have not released the victim's name.
So far, no arrests or word on a motive.