Tyleke Crawford is charged with several counts of rape, assault and corruption of minors.
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The Chester County District Attorney's Office said the alleged victims range from 6 to 17 years old.
Authorities said the assaults happened from 2014 and 2019.
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Crawford was arrested last year in connection with two other incidents involving sexual abuse of children and child pornography.
He is being held at Chester County Prison on $1 million bail. A preliminary hearing is set for January 26.
Anyone with information about this case is asked to call Chester County Detective David Nieves at 610-344-6866.