Scot Wills, 53, of New Britain, was arrested after a break-in on Meetinghouse Road in Hosrham on Friday.
Police were called out for a burglary in progress and found a rear door with a window smashed out.
Officers didn't find anyone there, but did have a vehicle description.
They later found that vehicle and took Wills into custody.
Investigators say Wills is an exterminator and was able to enter homes and neighborhoods without raising concerns.
He was remanded to Montgomery County prison in lieu of bail.
Police say they have found evidence that may link Wills to other crimes.