The lucky ticket was sold at Saibaba's Aashirwad Forever on West Swamp Road in Doylestown, according to lottery officials.
The retailer will get a $5,000 bonus for selling the winning ticket.
SEE ALSO: $1 million Powerball ticket sold in NJ as jackpot climbs to $1.9 billion
A second $1 million was also sold in Allegheny County.
The $1 million-winning tickets each matched five of the five white balls drawn, 28-45-53-56-69.
Winners are not known until prizes are claimed, and tickets are validated. Pennsylvania Powerball winners have one year from the drawing date to claim prizes, officials said.
The Powerball jackpot has currently reached an all-time record of $1.9 billion - $929.1 million cash value - ahead of Monday's drawing.