John Legend, Rita Ora, Ellie Goulding and Florence + the Machine are also due to perform at the "Sound of Change Live" show at Twickenham Stadium on June 1.
James Franco, Blake Lively and Jada Pinkett Smith have been lined up as presenters.
The concert is raising funds for Chime for Change, a Gucci-backed campaign to support projects improving health, education and justice for women around the world.
Organizers said Thursday that concertgoers will be able to choose which projects they want to support when they buy their tickets. Partner organizations include UNICEF, the Global Fund for Women and Plan International.
